Publication number: 09278598
Date of publication of application: 28.10.1997
Application number: 08112066
Date of filing: 09.04.1996
Applicant: TAKAMI TOMOHIDE, INO SHOZO
Inventor: TAKAMI TOMOHIDE, INO SHOZO
MICELLE TYPE METAL FINE PARTICLE AND ITS PRODUCTION
Abstract:
PROBLEM TO BE SOLVED: To obtain fine particles capable of using metal
fine particles, which have been limited in use method and field hitherto,
in various fields by absorbing molecular chain of an organic substance
onto the surface of metal fine particles, and covering metal fine particles
in micelle state.
SOLUTION: Micelle type metal fine particles 1 absorbing molecular chain
3 of organic substance having affinity for metal surface on the surface
of multiple twin crystal particles 2 having 1-200 nm particle diameter exhibit
properties based on the terminal functional group 4 of a molecular chain
3. As the metal fine particles, various kinds of metal fine particles such
as chromium, ZnTe, selenium, aluminum and copper can be used and especially,
twin crystal particles of gold, silver, nickel, palladium, platinum, etc.,
are preferable. An alkanethiol such as mercaptoacetic acid or beta-mercaptopropionic
acid is used as the molecular chain 3 of the organic substance and carbon
number of the alkyl chain is 2-18. Micelle type metal fine particles soluble
in water are obtained by using a hydrophilic group such as hydroxyl group,
carboxyl group, methyl group or phenyl group as the terminal functional
group 4 of the molecular chain 3. Multiple twin crystal particles 2 are
obtained by vacuum deposition onto substrate surface.